Shao finished with 13 points, while Zhao Xuetong and Hu Yueming each had 11.
Bolivia couldn't take a trick and Jose Carrasco gifted Brazil their fourth goal by deflecting a Philippe Coutinho cross into his own net.
The American improved her 2020 record in majors to a spectacular 16-1 after the win, during which she avoided the need for a deciding set and saved 10 of 12 breakpoints to seal the victory.
Henan guard Feng Song was on fire from outside the paint, draining four 3-pointers in a row to score all of her 14 points in the third quarter.
The Azzurri will take on Poland and the Netherlands on October 11 and 14. Enditem
Kvitova arrived for the match against the world No. 66 Siegemund as statistically the best server of this year's French Open remaining women's players, both in terms of ace struck and percentage of service games won.
Henrique completed the turnaround when his low shot after a counterattack rebounded in off the left post.
The tables turned 10 minutes later when the Irish were in a similar situation and beat Slovakia goalkeeper Marek Rodak but Juraj Kucka deflected the ball away to safety.
In the Shaanxi charity football tournament, Wang helped her teammates collect more than three million yuan (around 440,000 million U.S. dollars) to support the education of poor students in the province.
The Paris Saint-Germain forward provided two assists and showed no signs of the back injury that forced him to miss Brazil's last two training sessions before the match at Corinthians Arena.
But he proved again that once he walks onto the clay court, he is the man to beat.